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KAYOCA AUTO BODY 1-20-23 SUBMITTAL_v1-APPROVED (1)
C1 N 30500 SUMMERSIDE ST.MURRIETA, CA. 92563951-265-1618543 BIRCH ST UNIT AKAYOCA AUTO BODY TILAKE ELSINORE, CA 92530SITE PLAN C1 N 30500 SUMMERSIDE ST.MURRIETA, CA. 92563951-265-1618543 BIRCH ST UNIT AKAYOCA AUTO BODY TILAKE ELSINORE, CA 92530SITE PLAN A1 N 30500 SUMMERSIDE ST.MURRIETA, CA. 92563951-265-1618543 BIRCH ST UNIT AKAYOCA AUTO BODY TILAKE ELSINORE, CA 92530FLOOR PLAN A230500 SUMMERSIDE ST.MURRIETA, CA. 92563951-265-1618543 BIRCH ST UNIT AKAYOCA AUTO BODY TILAKE ELSINORE, CA 92530 A330500 SUMMERSIDE ST.MURRIETA, CA. 92563951-265-1618543 BIRCH ST UNIT AKAYOCA AUTO BODY TILAKE ELSINORE, CA 92530 05/23/2016Revision: Page: 1 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: Bulldog Aerosol Adhesion PromoterProduct Name: W. M. BarrCompany Name: 2105 Channel Avenue Memphis, TN 38113 3E 24 Hour Emergency ContactEmergency Contact:(800)451-8346 W.M. Barr Customer ServiceInformation:(800)398-3892 (901)775-0100 Phone Number: Paint adhesion.Intended Use: www.wmbarr.comWeb site address: ETPO123, ETPO123B, ETPO123BCNProduct Code: 1. PRODUCT AND COMPANY IDENTIFICATION This product is regulated by the United States Consumer Product Safety Commission and is subject to certain labeling requirements under the Federal Hazardous Substances Act. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS). The product label also includes other important information, including directions for use, and should always be read in its entirety prior to using the product. Additional Information 2. HAZARDS IDENTIFICATION P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P211: Do not spray on an open flame or any other ignition source. P251: Pressurized container: Do not pierce or burn, even after use. P260: Do not breathe gas/mist/vapors/spray. GHS Precaution Phrases: H222: Extremely flammable aerosol. H280: Containers gas under pressure; may explode if heated. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H341: Suspected of causing genetic defects. H351: Suspected of causing cancer, inhalation. H361: Suspected of damaging fertility or the unborn child. H372: Causes damage to organs through prolonged or repeated exposure. HUS1: May displace oxygen and cause rapid suffocation. GHS Hazard Phrases: Flammable Aerosols, Category 1 Gas Under Pressure, Liquefied gas Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Skin Sensitization, Category 1 Germ Cell Mutagenicity, Category 2 Carcinogenicity, Category 2 Toxic To Reproduction, Category 2 Specific Target Organ Toxicity (single exposure), Category 3 Specific Target Organ Toxicity (repeated exposure), Category 1 Simple Asphyxiant DangerGHS Signal Word: Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 2 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P281: Use personal protective equipment as required. P302+352: IF ON SKIN: Wash with plenty of soap and water. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+313: IF exposed or concerned: Get medical attention/advice. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical attention/advice if you feel unwell. P321: Specific treatment see label. P332+313: If skin irritation occurs, get medical advice/attention. P333+313: If skin irritation or rash occurs, seek medical advice/attention. P337+313: If eye irritation persists, get medical advice/attention. P362: Take off contaminated clothing and wash before re-use. P363: Wash contaminated clothing before reuse. GHS Response Phrases: P403+233: Store container tightly closed in well-ventilated place. P405: Store locked up. P410+403: Protect from sunlight and store in well-ventilated place. P412: Do not expose to temperatures exceeding 50 ºC/122 ºF. P501: Dispose of contents/container according to local, state and federal regulations. GHS Storage and Disposal Phrases: Hazard Rating System:Instability Special Hazard Health FlammabilityHEALTH FLAMMABILITY PPE PHYSICAL 2 0 4 * X 2 4 0 NFPA:HMIS: This material is classified as hazardous under OSHA regulations.OSHA Regulatory Status: INHALATION ACUTE EXPOSURE EFFECTS: Vapor Harmful. May cause dizziness, headache, irritation of the upper respiratory tract and lungs, irritation and injury to mucous membranes, watering of the eyes, weakness, drowsiness, nausea, loss of coordination, numbness in fingers, arms and legs, depression of the central nervous system, pulmonary edema, shortness of breath, loss of appetite, fatigue, stupor, anesthesia, narcosis, vomiting, lightheadedness, liver and kidney injury, insensibility and other central nervous system effects, blood disorders, nose tumors, brain damage, giddiness, olfactory changes, confusion, hearing impairment, slurred speech, coughing, hallucinations, irregular heartbeat, unconsciousness, coma, and death. Intentional misuse of this product by deliberately concentrating and inhaling vapors can be harmful or fatal. SKIN CONTACT ACUTE EXPOSURE EFFECTS: This product is a skin irritant. Product may be absorbed through the skin. May cause irritation, drying and cracking of the skin, defatting of the skin, dermatitis, itching, redness, swelling, tissue damage, inflammation, numbness in fingers and arms, discomfort or pain, erythema. May be absorbed readily to produce symptoms similar to those listed under ingestion. EYE CONTACT ACUTE EXPOSURE EFFECTS: This material is an eye irritant. May cause redness, tearing, corneal clouding, discomfort Potential Health Effects (Acute and Chronic): Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 3 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: Diseases of the skin, liver, kidneys, cardiovascular system, and central nervous system.Medical Conditions Generally Aggravated By Exposure: or pain with excessive blinking and tear production, excess redness and possible slight swelling of the conjunctiva, stinging, conjunctivitis, visual intolerance to light. If not promptly removed, will injure eye tissue, which may result in permanent damage. INGESTION ACUTE EXPOSURE EFFECTS: Harmful or fatal if swallowed. May cause dizziness, headache, drowsiness, nausea, weakness, loss of coordination, irritation to mouth, throat and stomach, vomiting, gastrointestinal irritation, diarrhea, loss of appetite, pain and discomfort, cough and hoarseness, salivation, changes in white blood cells, burning sensation in mouth and stomach, unconsciousness and coma. Ingestion of significant quantities may result in red blood cell hemolysis. CHRONIC EXPOSURE EFFECTS: Reports have associated repeated and prolonged overexposure to solvents with neurological and other physiological damage. Prolonged skin contact may result in absorption of a harmful amount of this material. Prolonged or repeated contact may cause dermatitis. May cause dizziness, headaches, weakness, eye irritation, drying and cracking of the skin, dermatitis, fatigue, nausea, numbness in the hands and feet, permanent central nervous system changes, some loss of memory, liver and kidney damage, blood disorders, thyroid effects, enlarged liver, and irritation to the respiratory tract. Prolonged or repeated contact may cause skin irritation, even a burn. Prolonged exposure may cause slight swelling of the conjunctiva, blurring of vision may occur. Prolonged skin contact may cause mild to moderate redness and swelling. CAS # Hazardous Components (Chemical Name) 3. COMPOSITION/INFORMATION ON INGREDIENTS Concentration 108-88-3 Toluene {Benzene, Methyl-; Toluol} 25.0 -50.0 % 115-10-6 Methyl ether {Dimethyl ether} <35.0 % 78-93-3 Methyl ethyl ketone {MEK; 2-Butanone} <10.0 % 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} <10.0 % 123-86-4 Butyl acetate {n-Butyl acetate. Acetic acid, Butyl ester} <10.0 % 1321-74-0 Divinyl benzene (Benzene, Diethenyl-) < 3.0 % 100-42-5 Styrene {Phenylethylene; Vinyl benzine; Styrol} < 3.0 % 97-63-2 Ethyl methacrylate {2-Propenoic acie, 2-methyl-, ethyl ester} < 2.0 % 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} < 2.0 % 111-76-2 Ethanol, 2-Butoxy- {Ethylene glycol n-butyl ether, (a glycol ether)} < 2.0 % Specific percentage of composition is being withheld as a trade secret.Additional Chemical Information Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 4 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: 4. FIRST AID MEASURES INHALATION: If user experiences breathing difficulty, move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists. EYE CONTACT: Immediately flush eyes with water for at least 15 minutes. Remove contact lenses if worn. Seek medical attention. INGESTION: If swallowed, do NOT induce vomiting. Call a physician, hospital emergency room, or poison control center immediately. Never give anything by mouth to an unconscious person. Emergency and First Aid Procedures: Primary Routes of Exposure: Inhalation, Skin ContactSigns and Symptoms Of Exposure: 5. FIRE FIGHTING MEASURES Flash Pt:42.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH approved or equivalent) and full protective gear. Storage containers exposed to fire should be kept cool with water spray to prevent pressure build-up. Stay away from heads of containers that have been exposed to intense heat or flame. Fire Fighting Instructions: CPSC FLAMMABILITY: Flammable Aerosol Flashpoint of dimethyl ether: -42 F (SCC) Flashpoint of liquid product: 42 F (SCC) Danger! Flammable! Keep away from heat, sparks, flame, and all other sources of ignition. Do not smoke. Extinguish all flames and pilot lights, and turn off stoves, heaters, electric motors and all other sources of ignition during use and until all vapors are gone. Beware of static electricity that may be generated by synthetic clothing and other sources. Vapors can travel to a source of ignition and flash back. Flammable Properties and Hazards: Autoignition Pt:No data. Explosive Limits:LEL: No data. UEL: No data. LEVEL 3 AEROSOL Use carbon dioxide, dry powder, or foam.Suitable Extinguishing Media: Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 5 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: 6. ACCIDENTAL RELEASE MEASURES Clean up: Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Shut off ignition sources; keep flares, smoking or flames out of hazard area. Use non-sparking tools. Use proper bonding and grounding methods for all equipment and processes. Keep out of waterways and bodies of water. Be cautious of vapors collecting in small enclosed spaces, sewers, low lying areas, confined spaces, etc. Small spills: Take up with sand, earth or other noncombustible absorbent material and place in a container where applicable. Large spills: Dike far ahead of spill for later disposal. Waste Disposal: Dispose in accordance with applicable local, state and federal regulations. Steps To Be Taken In Case Material Is Released Or Spilled: 7. HANDLING AND STORAGE Read carefully all cautions and directions on product label before use. Since empty container retains residue, follow all label warnings even after container is empty. Dispose of empty container according to all regulations. Do not reuse this container. Do not use this product near any source of heat or open flame, furnace areas, pilot lights, stoves, etc. Do not use in small enclosed spaces, such as basements and bathrooms. Vapors can accumulate and explode if ignited. Do not spread this product over large surface areas because fire and health safety risks will increase dramatically. Precautions To Be Taken in Handling: Store in a cool dry place. Avoid extreme high or low temperatures.Precautions To Be Taken in Storing: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits PEL: 200 ppm STEL: 500 ppm/(10min) CEIL: 300 ppm TLV: 50 ppm 108-88-3 Toluene {Benzene, Methyl-; Toluol} No data. No data. No data. 115-10-6 Methyl ether {Dimethyl ether} No data. PEL: 200 ppm TLV: 200 ppm STEL: 300 ppm 78-93-3 Methyl ethyl ketone {MEK; 2-Butanone} No data. PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No data. PEL: 150 ppm TLV: 150 ppm STEL: 200 ppm 123-86-4 Butyl acetate {n-Butyl acetate. Acetic acid, Butyl ester} No data. No data. TLV: 10 ppm 1321-74-0 Divinyl benzene (Benzene, Diethenyl-) No data. Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 6 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: PEL: 100 ppm STEL: 600 ppm/(5min/3hr) CEIL: 200 ppm TLV: 20 ppm STEL: 40 ppm 100-42-5 Styrene {Phenylethylene; Vinyl benzine; Styrol} No data. No data. No data. 97-63-2 Ethyl methacrylate {2-Propenoic acie, 2-methyl-, ethyl ester} No data. PEL: 100 ppm TLV: 100 ppm STEL: 125 ppm 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} No data. PEL: 50 ppm TLV: 20 ppm 111-76-2 Ethanol, 2-Butoxy- {Ethylene glycol n-butyl ether, (a glycol ether)} No data. For use in areas with inadequate ventilation or fresh air, wear a properly maintained and properly fitted NIOSH approved respirator for organic solvent vapors. For OSHA controlled work places and other regular users - Use only with adequate ventilation under engineered air control systems designed to prevent exceeding the appropriate TLV. A dust mask does not provide protection against vapors. Respiratory Equipment (Specify Type): A faceshield or chemical splash goggles should be worn to prevent eye contact.Eye Protection: Wear gloves with as much resistance to the chemical ingredients as possible. Glove materials such as nitrile rubber may provide protection. Glove selection should be based on chemicals being used and conditions of use. Consult your glove supplier for additional information. Gloves contaminated with product should be discarded and not reused. Protective Gloves: Various application methods can dictate use of additional protective safety equipment, such as impermeable aprons, etc., to minimize exposure. Other Protective Clothing: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use only with adequate ventilation to prevent buildup of vapors. Do not use in areas where vapors can accumulate and concentrate, such as basements, bathrooms or small enclosed areas. Whenever possible, use outdoors in an open air area. If using indoors open all windows and doors and maintain a cross ventilation of moving fresh air across the work area. If strong odor is noticed or you experience slight dizziness, headache, nausea or eye-watering -- STOP -- ventilation is inadequate. Leave area immediately and move to fresh air. Engineering Controls (Ventilation etc.): Wash hands thoroughly after use and before eating, drinking, smoking, or using the restroom. Do not eat, drink, or smoke in the work area. Discard any clothing or other protective equipment that cannot be decontaminated. Facilities storing or handling this material should be equipped with an emergency eyewash and safety shower. Work/Hygienic/Maintenance Practices: Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 7 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: 9. PHYSICAL AND CHEMICAL PROPERTIES Physical States:[ X ] Gas [ X ] Liquid [ ] Solid Melting Point:No data. Boiling Point:No data. Autoignition Pt:No data. Flash Pt:42.00 F Method Used: Setaflash Closed Cup (Rapid Setaflash) Explosive Limits:LEL: No data. UEL: No data. Specific Gravity (Water = 1): 0.895 - 0.905 Density: 7.49 LB/GL Hazy, Light YellowAppearance and Odor: Vapor Pressure (vs. Air or mm Hg): <=31 MM HG at 20.0 C Vapor Density (vs. Air = 1):> 1 Evaporation Rate:~ 1 Solubility in Water:No data. Percent Volatile:90.4 % by weight. 10. STABILITY AND REACTIVITY No data available.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Incompatible with strong oxidizing agents, strong caustics, acids, strong bases, hydrogen peroxide, nitric acid, nitrates, sulfuric acid, amines, chemically active metals, salts, aldehydes, ammonia, and halogens. Incompatibility - Materials To Avoid: Thermal decomposition may produce carbon monoxide, carbon dioxide, acrylic monomers, acrid smoke and fumes. Hazardous Decomposition or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: 11. TOXICOLOGICAL INFORMATION Product has not been tested as a whole. Refer to section 2 for acute and chronic health effects. Toxicological Information: CAS# 108-88-3: Reproductive Effects:, TCLo, Inhalation, Rat, 800.0 MG/M3, 6 H, female 14-20 day(s) after conception. Result: Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Effects on Newborn: Behavioral. - Brazilian Journal of Medical and Biological Research., Vol/p/yr: 23,533, 1990 Standard Draize Test, Eyes, Species: Rabbit, 2.000 MG, 24 H, Severe. Result: Effects on Embryo or Fetus: Other effects to embryo. Specific Developmental Abnormalities: Eye, ear. - Prehled Prumyslove Toxikologie, Marhold, J., Organicke Latky, Prague Czechoslovakia, Vol/p/yr: -,29, 1986 Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 8 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: CAS# 78-93-3: Standard Draize Test, Eyes, Human, 350.0 PPM. Result: Behavioral: Anticonvulsant. - Journal of Industrial Hygiene and Toxicology, Vol/p/yr: 25,282, 1943 CAS# 1330-20-7: Acute toxicity, LC50, Inhalation, Rat, 5000. PPM, 4 H. Result: Behavioral: Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Other changes. - Raw Material Data Handbook, Vol.1: Organic Solvents, 1974., National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Labor, Lehigh Univ., Bethlehem, PA 18015, Vol/p/yr: 1,123, 1974 Standard Draize Test, Eyes, Species: Rabbit, 5.000 MG, 24 H, Severe. Result: Behavioral: General anesthetic. Behavioral: Somnolence (general depressed activity). Behavioral: Irritability. - "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," , Institut Pro Vychovu Vedoucicn P, Marhold, J.V., Institut Pro Vychovu Vedoucicn, Pracovniku Chemickeho, Prumyclu Praha Czechoslovakia, Vol/p/yr: -,24, 1972 CAS# 100-41-4: Tumorigenic Effects:, TCLo, Inhalation, Rat, 750.0 ppm. Result: Tumorigenic: Carcinogenic by RTECS criteria. Kidney, Ureter, Bladder: Tumors. Standard Draize Test, Eyes, Species: Rabbit, 500.0 MG, Severe. Result: Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of implants). Effects on Fertility: Litter size (e.g.; # fetuses per litter; measured before birth). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). - American Journal of Ophthalmology., Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611, Vol/p/yr: 29,1363, 1946 CAS# 111-76-2: Acute toxicity, LC50, Inhalation, Rat, 450.0 PPM, 4 H. Result: Behavioral: Ataxia. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. - Toxicology and Applied Pharmacology, Academic Press, Inc., 1 E. First St., Duluth, MN 55802, Vol/p/yr: 68,405, 1983 Acute toxicity, LD50, Skin, Species: Rabbit, 220.0 MG/KG. Result: Effects on Embryo or Fetus: Extra embryonic structures (e.g., placenta, umbilical cord). Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 9 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP ACGIH A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans ACGIH A4 - Not Classifiable as a Human Carcinogen. IARC 2B - Possibly Carcinogenic to Humans IARC 3: Not Classifiable as to Carcinogenicity in Humans. Carcinogenicity/Other Information: IARC ACGIH OSHA Effects on Embryo or Fetus: Other effects to embryo. Specific Developmental Abnormalities: Musculoskeletal system. - Dow Chemical Company Reports., Dow Chemical USA, Health and Environment Research, Toxicology Research Lab, Midland, MI 48640, Vol/p/yr: MSD-46, Acute toxicity, LD50, Oral, Rat, 250.0 mg/kg. Result: Lungs, Thorax, or Respiration:Changes in pulmonary vascular resistance. Standard Draize Test, Eyes, Species: Rabbit, 100.0 MG, Severe. Result: Effects on Newborn: Apgar score (human only). Effects on Newborn: Other neonatal measures or effects. Effects on Newborn: Drug dependency. - American Journal of Ophthalmology., Ophthalmic Pub. Co., 435 N. Michigan Ave., Suite 1415, Chicago, IL 60611, Vol/p/yr: 29,1363, 1946 108-88-3 Toluene {Benzene, Methyl-; Toluol} n.a. 3 A4 n.a. 115-10-6 Methyl ether {Dimethyl ether} n.a. n.a. n.a. n.a. 78-93-3 Methyl ethyl ketone {MEK; 2-Butanone} n.a. n.a. n.a. n.a. 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} n.a. 3 A4 n.a. 123-86-4 Butyl acetate {n-Butyl acetate. Acetic acid, Butyl ester} n.a. n.a. n.a. n.a. 1321-74-0 Divinyl benzene (Benzene, Diethenyl-) n.a. n.a. n.a. n.a. 100-42-5 Styrene {Phenylethylene; Vinyl benzine; Styrol} Possible 2B A4 n.a. 97-63-2 Ethyl methacrylate {2-Propenoic acie, 2-methyl-, ethyl ester} n.a. n.a. n.a. n.a. 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} n.a. 2B A3 n.a. 111-76-2 Ethanol, 2-Butoxy- {Ethylene glycol n-butyl ether, (a glycol ether)} n.a. 3 A3 n.a. Product has not been tested as a whole.General Ecological Information: 12. ECOLOGICAL INFORMATION Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 10 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: Dispose of in accordance with all applicable local, state, and federal regulations.Waste Disposal Method: 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION Aerosols, Flammable, Ltd. Qty.DOT Proper Shipping Name: 2.1 FLAMMABLE GASDOT Hazard Class: UN1950UN/NA Number: LAND TRANSPORT (US DOT): IMDG/IMO Shipping Name: MARINE TRANSPORT (IMDG/IMO): |N|UN Number: Packing Group: 2.1 - FLAMMABLE GASHazard Class: |IMDG MFAG Number: |IMDG EMS Page: CAS # Hazardous Components (Chemical Name) 15. REGULATORY INFORMATION S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 108-88-3 Toluene {Benzene, Methyl-; Toluol} No Yes 1000 LB Yes 115-10-6 Methyl ether {Dimethyl ether} No No No 78-93-3 Methyl ethyl ketone {MEK; 2-Butanone} No Yes 5000 LB No 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} No Yes 100 LB Yes 123-86-4 Butyl acetate {n-Butyl acetate. Acetic acid, Butyl ester} No Yes 5000 LB No 1321-74-0 Divinyl benzene (Benzene, Diethenyl-) No No No 100-42-5 Styrene {Phenylethylene; Vinyl benzine; Styrol} No Yes 1000 LB Yes 97-63-2 Ethyl methacrylate {2-Propenoic acie, 2-methyl-, ethyl ester} No Yes 1000 LB No 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} No Yes 1000 LB Yes 111-76-2 Ethanol, 2-Butoxy- {Ethylene glycol n-butyl ether, (a glycol ether)} No No Yes-Cat. N230 [X] Yes [ ] No Acute (immediate) Health Hazard [X] Yes [ ] No Chronic (delayed) Health Hazard [X] Yes [ ] No Fire Hazard [X] Yes [ ] No Sudden Release of Pressure Hazard [X] Yes [ ] No Reactive Hazard This material meets the EPA 'Hazard Categories' defined for SARA Title III Sections 311/312 as indicated: CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 108-88-3 Toluene {Benzene, Methyl-; Toluol} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 8A CAIR; CA PROP.65: Yes: RDTox(F) 115-10-6 Methyl ether {Dimethyl ether} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 78-93-3 Methyl ethyl ketone {MEK; 2-Butanone} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No Licensed to W.M. Barr and Company GHS format 05/23/2016Revision: Page: 11 Bulldog Aerosol Adhesion Promoter SAFETY DATA SHEET 05/04/2015Supersedes Revision: 1330-20-7 Xylene (mixed isomers) {Benzene, dimethyl-} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: No 123-86-4 Butyl acetate {n-Butyl acetate. Acetic acid, Butyl ester} CAA HAP,ODC: No; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: No 1321-74-0 Divinyl benzene (Benzene, Diethenyl-) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 100-42-5 Styrene {Phenylethylene; Vinyl benzine; Styrol} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory, 8A CAIR; CA PROP.65: Yes: Canc. 97-63-2 Ethyl methacrylate {2-Propenoic acie, 2-methyl-, ethyl ester} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 100-41-4 Ethylbenzene {Ethylbenzol; Phenylethane} CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Yes - Inventory; CA PROP.65: Yes: Canc. 111-76-2 Ethanol, 2-Butoxy- {Ethylene glycol n-butyl ether, (a glycol ether)} CAA HAP,ODC: Yes - Cat.; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No 16. OTHER INFORMATION No data available.Additional Information About This Product: The information contained herein is presented in good faith and believed to be accurate as of the effective date shown above. This information is furnished without warranty of any kind. Employers should use this information only as a supplement to other information gathered by them and must make independent determination of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. Any use of this data and information must be determined by the user to be in accordance with applicable federal, state and local laws and regulations. Company Policy or Disclaimer: 05/23/2016Revision Date: W.M. Barr EHS Dept (901)775-0100Preparer Name: Licensed to W.M. Barr and Company GHS format ! " #$ % & ''&& % & '' !# ( )* (* +',& + ,&-+ ! " " " " # ". /- * + & 01* /- 2 234%% $ % & % 1 *- * + * )5& )5& " ! ' " '&& '%% , ! 3- , #$ ,,, && $ ! ' " !& #$ ' " '&& %% !,&& #$ 678'&& && % && ! 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LEDT8-48-BLST 15.9 watt T-series Fluorescent Style LED Tube Quick Summary Listing: United States & Canada Listed for United States and Canada Lamp Type: LED T8-Style Tube UL-1993 Base: G13 Bi-Pin UL-1993 CLS Dimensions: 47.24"-L x 1.02"-OD CAN/CSA C22.2 No 137 Weight: 0.77 lbs (350 grams)CAN/CSA C22.2 No 137 CLS Voltage: 100-277 Volts AC, 50/60Hz 130 Lm/W efficiency Watts: 15.9 watts Certified to Canadian Standards Total Lumens: 2,000 LEL Listed Luminous Efficiency: 130 Lm/W 80% Lumen Retention @ 50,000+ Hours Lamp Life Expectancy: 50,000+ Hours Internal Driver Color Temperature: 4000k or 5000k Single End Powered Color Rendering Index: >82.5 Beam angle: 140° Lighting Configuration: Flood Pattern Lens: Frosted Power Efficiency: 90%Special Orders- Requirements Power Factor: >0.98 Contact us for special requirements Ambient Temperature Rating: -20°C to +45°C Toll Free: 1-800-369-6671 Materials: Aluminum housing, polycarbonate lens Intl: 1-903-270-1187 Ingress Protection: IP20 E-mail: sales@larsonelectronics.com The LaUVRQ ElecWURQicV LEDT8-48-BLST 15.9 ZaWW T-VeUieV LED WXbe lamS iV aQ e[celleQW chRice fRU XSgUadiQg e[iVWiQg T8 flXRUeVceQW lamS fi[WXUeV WR LEDV aV Zell aV a diUecW UeSlacemeQW fRU RXU RZQ LED lighW fi[WXUeV. 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IQWHUQDOO\, \RX VLPSO\ EULQJ WKH EODFN ZLUH WR RQH SLQ DQG WKH ZKLWH ZLUH WR WKH RWKHU. 7KH SRO\FDUERQDWH 1 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax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LED ODPSV, OLNH WKH LED78-48-BLS7 DUH GLUHFWLRQDO, ZKLFK HOLPLQDWHV WKH QHHG IRU EDFN PRXQWHG UHIOHFWRUV DQG UHGXFHV ZDVWHG DQG ORVW OLJKW. 7KHVH DUH WKH VHFRQG JHQHUDWLRQ RI RXU 15.9 ZDWW LED WXEHV. EIILFLHQF\ IRU WKLV LED ODPS LV 130 OXPHQV SHU ZDWW, IRU D WRWDO RI 2,000 OXPHQV SHU EXOE. :H RIIHU D FKRLFH RI 4000K DQG 5000N FRORU WHPSHUDWXUHV DQG IURVWHG OHQVHV. 7KH LED78 VHULHV RI LED ODPSV DUH GHVLJQHG IRU GLUHFW UHSODFHPHQW RI 4IW IOXRUHVFHQW IL[WXUHV ZLWK G13 EDVHV IRU UHSODFLQJ IRXU IRRW 78, 78 KLJK RXWSXW, 712, 712 KLJK RXWSXW, DQG 712 YHU\ KLJK RXWSXW IORUHVFHQW ODPSV. AGGLWLRQDOO\, WKHVH ODPSV FDQ EH XVHG LQ IL[WXUHV WKDW FXUUHQWO\ XVH D G5 WR G13 DGDSWHU VRFNHW XVLQJ 75 ODPSV. POHDVH QRWH, WKLV WXEH LV 47" LQ OHQJWK DQG ZLOO QRW ILW SURSHUO\ LQ IL[WXUHV GHVLJQHG WR DFFHSW 45" 75 ODPSV ZLWKRXW DGDSWHUV. 7KHVH LED IOXRUHVFHQW WXEH UHSODFHPHQWV FDQ EH XVHG DV XSJUDGHV RU UHSODFHPHQWV WR RXU RZQ H[SORVLRQ SURRI IOXRUHVFHQW OLJKWV, H[SORVLRQ SURRI SDLQW VSUD\ ERRWK OLJKWV DV ZHOO DV DQ\ RWKHU 7 VHULHV OLJKW IL[WXUH WKH RSHUDWRU DOUHDG\ KDV LQ KRXVH. :H KDYH VSHFLDOO\ GHVLJQHG WKHVH IRU RXU H[SORVLRQ SURRI OLJKW IL[WXUHV, KRZHYHU, WKH\ FDQ EH XVHG DV UHSODFHPHQWV LQ VWDQGDUG IOXRUHVFHQW OLJKW IL[WXUHV ZLWK QR QHHG WR UHPRYH WKH EDOODVWV RU ZLULQJ DURXQG WKHP. LED Lamp Benefits 2 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 1. 50,000 hour lifespan. 2. Can SAVE 50% or more on energy. 3. Qualifies retrofit projects for financial incentives, including utility rebates, tax credits and energy loan programs. 4. Reduces energy use and prolongs life-spans of peripheral cooling units (A/C, refrigeration) 5. 100% recyclable. 6. No toxins-lead, mercury. 7. No UV light, infrared radiation or CO2 emissions. 8. Qualifies buildings for LEED and other sustainable business certifications. 9. Bright, even light maintains consistent color over time. 10. Instant on/off - No flickering, delays or buzzing. 11. Very good color rendering. 12. Vibration/impact resistant. 13. Significantly cooler operation. 14. Less frequent outages, higher output improves workplace safety. 15. Brings out natural appearance of products in sales or manufacturing applications. 16. Preserves integrity of retail products... no heat damage to formulations or thermal fade of branded packaging in display cases. 17. Unlimited indoor applications for overhead lighting, retail fixtures, signage, custom lighting accents, manufacturing and general area illumination. 18. Easily retrofit existing conventional light fixtures, simplifies troffers since no ballasts needed. Durable enough for portable use in exhibitions and trade shows. 3 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 Frequently Asked Questions (FAQ) 4 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 5 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 6 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 7 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 Warranty: 12 Months Options: LEDT8-48-BLST-Color Temp Example: LEDT8-48-BLST-40K Color Temp 4000K -40K 5000K -50K 8 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 Links (Click on the below items to view): - Canadian CEC Certificate (Commonly referred to as CSA Certificate) - USA NEC Certificate (Commonly referred to as UL Certificate) - HigResPic1 - HigResPic2 - HigResPic3 - HigResPic4 - HigResPic9 - Video1 - ISO 9001 Certification - Business Certificate - Shipping Time Map 9 Larson Electronics LLC 9419 E US HWY 175, Kemp, TX 75143 Phone: 800.369.6671 www.LarsonElectronics.com Email: sales@LarsonElectronics.com Fax: 903.498.3364 SAFETY DATA SHEET Prepared according to USA OSHA Hazcom 2012 / Canada WHMIS 2015 Date Issued : 08/13/2019 SDS No : LVAPCQ Low VOC Surface Cleaner_ENG Date Revised : 08/13/2019 Revision No : 1 LVAPCQ LOW VOC SURFACE CLEANER 1. IDENTIFICATION Product Name: LVAPCQ LOW VOC SURFACE CLEANER Product Description: Surface Cleaner & Multi-Purpose Solvent, Low VOC 946 mL / 1 qt US General Use: Surface Cleaners Product Stock/Code: LVAPCQ / 8009 Chemical Family: Water-based Solvent Molecular Formula: Mixture Manufacturer / Supplier Emergency Telephone Numbers (24 hour) Dominion Sure Seal Ltd. 6175 Danville Road, Mississauga Ontario, Canada L5T 2H7 Fax: 905-670-5174 www.dominionsureseal.com Customer Service: 905-670-5411 CANUTEC : (613) 996-6666 CHEMTREC : (800) 424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture The classification and label elements stated below were prepared in accordance with the USA OSHA Hazard Communication Standard (29 CFR 1910.1200; Hazcom 2012) and the Canadian WHMIS regulations (Hazardous Products Regulations; WHMIS 2015). This information may be different from the actual product label information for labels that are regulated by other agencies. Health hazards: Eye Irritation, Category 2 Physical hazards: Flammable Liquids, Category 2 Label elements Hazardous components for labelling: Acetone and Isopropyl alcohol Flame Exclamation mark Signal Word: DANGER Hazard statement(s) H225: Highly flammable liquid and vapour. Page 1 of 10 H319: Causes serious eye irritation. Precautionary statement(s) Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P240: Ground and bond container and receiving equipment. P241: Use explosion-proof electrical, ventilating and lighting equipment. P242: Use non-sparking tools. P243: Take action to prevent static discharges. P264: Wash hands thoroughly after handling. P280: Wear eye protection. Response: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P370+P378: In case of fire: Use dry chemical or foam to extinguish. Storage: P403+P235: Store in a well-ventilated place. Keep cool. Disposal: P501: Dispose of contents/container in accordance with applicable local, regional and/or national regu lations. Hazards Not Otherwise Classified: No data available. Emergency Overview Immediate concerns: Flammable liquid and vapor. Causes serious eye irritation. Substance does not generally irritate and is only mildly irritating to the skin. Vapours may cause drowsiness and dizziness. Comments: See sections 9 and 10 for more detailed informatio n on physicochemical effects. See section 11 for more detailed information on health effects. See sections 12 for more detailed information on environmental effects. The actual container label may not include the above label elements. The labeling shown above applies to products used solely for industrial / professional use. Consumer products should be labeled in accordance with the Canadian Consumer Chemicals and Containers Regulations and US Consumer Product Safety Commission regulations. Consumer product labeling takes precedence over Canadian WHMIS 2015 and OSHA Hazcom 2012 Hazard Communication labeling. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.%CAS number Acetone 5 - 10 67-64-1 Isopropyl alcohol 1 - 3 67-63-0 Comments: There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the product and hence require reporting in this section. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water. Get m edical attention, if irritation persists. Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. Remove LVAPCQ LOW VOC SURFACE CLEANER Page 2 of 10 contaminated clothing and wash before reuse. Ingestion: Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention required. Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain medical attention if breathing difficulty persists. Signs and Symptoms of Overexposure Eye Contact: Contact causes serious eye irritation. Symptoms ma y include pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Skin Contact: Substance does not generally irritate and is only mildly irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Ingestion: Substance may be harmful if swallowed. Inhalation: High vapor or spray mist concentrations may be harmful if inhaled. May cause headaches and dizziness. High vapor concentrations may cause drow siness. Additional Information: No data available. 5. FIRE FIGHTING MEASURES Flammable Properties: Flammable Liquid. Can release vapors that form exp losive mixtures at temperatures at or above the flash point. Product can be ignited by static discharge. Extinguishing Media: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Hazardous Combustion Products: During a fire, irritating and highly toxic gases m ay be generated by thermal decomposition or combustion. Fire Fighting Procedures: Containers can build up pressure if exposed to hea t (fire). Fire Fighting Equipment: As in any fire, wear self-contained breathing appa ratus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. Sensitivity to Static Discharge: Product is sensitive to static discharge. Sensitivity to Mechanical Impact: Product is not sensitive to mechanical impact. 6. ACCIDENTAL RELEASE MEASURES Small Spill: Eliminate all ignition sources. Contain spilled li quid with sand or earth. DO NOT use combustible materials such as sawdust. Sweep up material being careful not to raise dust. Place in an appropriate disposal container and seal tightly. Environmental Precautions Water Spill: Do not discharge into drains/surface waters/groundwater. Land Spill: Avoid runoff into storm sewers and ditches which lead to waterways. Special Protective Equipment: Clean up spills immediately, observing precautions in Protective Equipment section 8. 7. HANDLING AND STORAGE General Procedures: Comply with all national, state, and local codes pertaining to the storage, handling, dispensing, and disposal of flammable liquids. Ensure thorough ventilation of stores and work areas. Handling: Do not use in the presence of open flame or spark. Wear recommended personal protective equipment. Use only in a well ventilated area. Do not breath v apors. Avoid contact with eyes, skin, and clothing. After handling, always wash hands thoroughly with soap and water. LVAPCQ LOW VOC SURFACE CLEANER Page 3 of 10 Storage: Keep away from heat, sparks and open flame. Protect from physical damage. Keep containers tightly closed, when not in use. Store in a cool place. Keep from freezing. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines OSHA / WHMIS 2015 HAZARDOUS COMPONENTS Occupational Exposure Limits Chemical Name Type ppm mg/m3 Acetone OSHA PEL TWA 1000 2400 ACGIH TLV TWA 500 1188 STEL 750 1782 NIOSH REL TWA 250 590 Isopropyl alcohol OSHA PEL TWA 400 980 ACGIH TLV TWA 200 491 STEL 400 984 NIOSH REL TWA 400 980 STEL 500 1225 Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Personal Protective Equipment Eyes and Face: Wear safety glasses with side shields (or goggles). Contact lenses should not be worn when working with this product. Eye wash fountains should be readily available to areas of use and handling. Skin Contact: Wear chemical resistant gloves. Respiratory: Generally not required. Wear respiratory protection if ventilation is inadequate. Protective Clothing: Wear protective clothing as necessary to prevent contact. Work Hygienic Practices: Use good personal hygiene practices. Wash hands be fore eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State : Liquid Odor : Ketone Odor Threshold : Not Available Appearance : Clear Color : Colourless pH : No data available. % Volatiles : 99+ % w/w Flash Point and Method : 15.5 °C Setaflash Closed Cup Flammable Limits : 2.5 to 12.8 Notes: Based on data for acetone. Autoignition Temperature : No data available. Vapor Pressure : 24 kPa (184 mm Hg) [Acetone] at 20°C LVAPCQ LOW VOC SURFACE CLEANER Page 4 of 10 Vapor Density : > 1 Boiling Point : 56 - 105 °C Freezing Point : Not Available Melting Point : Not Available Solubility in Water : Soluble Evaporation Rate (n-butyl acetate = 1) : > 1 Density : 0.96 - 1.00 g/ml at 20°C Viscosity : Not Available VOC Content : < 25 g/l, less exempt solvents [< 2.5% w/w] Oxidizing Properties : None Comments: VOC Compliance Statement VOC Content: (as supplied) 25 g/l (0.2 lb/gal) 2.5 % w/w Density:0.98 ± 0.02 g/ml Water Content:89.0 ± 0.5 % w/w Exempt Content:8.5 ± 0.5 % w/w (acetone) VOC Regulation:SCAQMD Rule 1143 – Consumer Paint Thinners & Multi-Purpose Solvents– California, USA Coating Category:Consumer Multi-Purpose Solvent The product VOC content meets the 25 g/l (0.21 lb/gal) limit for Consumer Multi-Purpose Solvents. California compliant. Do no t thin with solvents. VOC Regulation:CARB Consumer Product Regulations Coating Category:Multi-Purpose Solvent The product VOC content meets the current 3% w/w limit under the CARB Consumer Product Regulations for Multi-Purpose Solvents. California compliant. Do not thin with solvents. VOC Regulation:VOC Concentration Limits for Automotive Refinishing Products Regulations – Canada Coating Category:Surface Cleaners The product VOC content meets the 50 g/l (0.42 lb/gal) limit for Surface Cleaners. Canada compliant. Do not thin with solvents VOC Regulation:SCAQMD Rule 1151 - Motor Vehicle and Mobile Equipment Non-Assembly Line Coating Operations– California Coating Category:Surface Cleaners The product VOC content meets the 25 g/l (0.21 lb/gal) limit for Surface Cleaners. California compliant. Do not thin with solvents. 10. STABILITY AND REACTIVITY Reactive Hazard : No Hazardous Polymerization: Not expected to occur. Stability: Stable. Conditions to Avoid: Keep away from flames and incompatible materials. Keep away from flames and any object that sparks. Possibility of Hazardous Reactions: No data available. LVAPCQ LOW VOC SURFACE CLEANER Page 5 of 10 Hazardous Decomposition Products: Carbon Monoxide and other toxic vapors. Incompatible Materials: Oxidizing materials. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Chemical Name Oral LD 50 mg/kg(rat) Dermal LD 50 mg/kg(rabbit) Inhalation LC 50 mg/l Acetone 8400 5250(mouse) 5300(rabbit) >15,700 50.1(rat;8h) 44.0(mouse;4h) Isopropyl alcohol 4710-5840 4475(mouse) 5030(rabbit) 12,870 51.0(rat;8h) 72.6(rat;4h) Acute Toxicity - Dermal LD50 : Based on available ingredient data, the classifica tion criteria for Acute Dermal Toxicity are not met for this mixture. The calculated ATE is >2000 mg/kg. Acute Toxicity - Oral LD50 : Based on available ingredient data, the classifica tion criteria for Acute Oral Toxicity are not met for this mixture. The calculated ATE is >2000 mg/kg. Acute Toxicity - Inhalation LC50 : Based on available ingredient data, the classifica tion criteria for Acute Toxicity - inhalation are not met for this mixture. The calculated ATE is >20 mg/l/4h (vapours). Notes: < 1% of the mixture consists of an ingredient or ingredients of unknown acute toxicity. No additional toxicology information is available for this product itself. (See Component Toxicity Information). Primary Routes of Entry: Eye contact. Inhalation. Skin contact. Ingestion. Skin Irritation / Corrosion: Based on available data, the classification criter ia for skin irritation are not met for this mixture. Substance does not generally irritate and is only mildly irritating to the skin. Prolong ed or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Eye Irritation / Serious Eye Damage: Contains: Acetone and Isopropyl alcohol. Contact causes serious eye irritation. The mixture is classified as: Eye Irritant, category 2, based on summation of ingredient data (>10% ingredients classified as eye irritant, category 2). Symptoms may include pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Respiratory / Skin Sensitizer: Based on available data, the classification criter ia for skin/respiratory sensitization are not met for this mixture (< 0.1% ingredients classified as a skin sensitizer, category 1 or sub- category 1A and < 1.0% ingredients classified as a skin/respiratory sensitizer, sub-category 1B). Germ Cell Mutagenicity: Based on available data, the classification criter ia for Germ Cell Mutagenicity are not met for this mixture (< 0.1% ingredients classified as Germ Cell Mutagen, category 1A or 1B and < 1.0% ingredients classified as Germ Cell Mutagen, catego ry 2). Carcinogenicity Chemical Name NTP status IARC status OSHA status Other Acetone ------A4 (ACGIH) Isopropyl alcohol --3 ---- Notes: Based on available data, the classification criter ia for Carcinogenicity are not met for this mixture (< 0.1% ingredients classified as a Carcinogen, category 1 or 2). Reproductive Toxicity: Based on available data, the classification criter ia for Reproductive Toxicity are not met for this mixture (< 0.1% ingredients classified as Reproductive Toxicity, category 1 or 2). Specific Target Organ Toxicity - Single Exposure: Based on available data, the classification criter ia for Specific Target Organ Toxicity - Single Exposure are not met for this mixture (< 1.0% ingredients classified as LVAPCQ LOW VOC SURFACE CLEANER Page 6 of 10 Specific Target Organ Toxicity - Single Exposure, category 1 or 2 and < 20% summation of all ingredients classified as Specific Target Organ Toxicity - Single Exposure, category 3). Specific Target Organ Toxicity - Repeated Exposure: Based on available data, the classification criter ia for Specific Target Organ Toxicity - Repeated Exposure are not met for this mixture (< 1.0% ingredients classified as Specific Target Organ Toxicity - Repeated Exposure, category 1 or 2). Aspiration Hazard: Based on available data, the classification criter ia for Aspiration Hazard are not met for this mixture (< 10% ingredients classified as an Aspiration Hazard, category 1 and/or mixture viscosity > 20.5 mm2/s at 40 °C). 12. ECOLOGICAL INFORMATION Environmental Data: No data available. Ecotoxicological Information: No data available. Bioaccumulation/Accumulation: No data available. Distribution: No data available. Aquatic Toxicity (Acute): No data available. Chemical Fate Information: No data available. 13. DISPOSAL CONSIDERATIONS Disposal Method: Comply with applicable local, state or international regulations concerning solid or hazardous waste disposal and/or container disposal. Do not discharge substance/product into sewer system. Product Disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name : PAINT RELATED MATERIAL Primary Hazard Class/Division: 3 UN/NA Number : 1263 Packing Group : II Other Shipping Information: For products with an inner packaging < 5.0 L, this product may be shipped as a Limited Quantity. Vessel (IMO/IMDG) Shipping Name : PAINT RELATED MATERIAL UN/NA Number : 1263 Primary Hazard Class/Division: 3 Packing Group : II Marine Pollutant : None Note: For products with an inner packaging < 5.0 L, this product may be shipped as a Limited Quantity. Canadian Transportation of Dangerous Goods Regulations Shipping Name : PAINT RELATED MATERIAL UN/NA Number : 1263 Primary Hazard Class/Division: 3 LVAPCQ LOW VOC SURFACE CLEANER Page 7 of 10 Packing Group : II TDG Note: For products with an inner packaging < 5.0 L, this component may be shipped as a Limited Quantity as per TDG Section 1.17. 15. REGULATORY INFORMATION UNITED STATES SARA Section 311/312 Hazard Categories 311/312 HEALTH HAZARDS: Eye Irritation 311/312 Physical Hazards: Flammable Liquids EPCRA Section 313 Toxic Chemicals Chemical Name Wt. % CAS nu mber Isopropyl alcohol 1 - 3 67-63-0 EPCRA Section 302 Extremely Hazardous Substances EPCRA Status: This product contains no listed extremely hazardous substances that are subject to the reporting requirements of SARA Title III, Section 302. CERCLA Hazardous Substances and Reportable Quantities (RQ) Chemical Name Wt. %RQ Acetone 5 - 10 5,000 TSCA (The Toxic Substances Control Act) TSCA Status: All components are included or are otherwise exempt from inclusion on this inventory. CAA 112(b) - Hazardous Air Pollutants CAA 112(r) - List of Substances for Accidental Rele ase Prevention: This product contains no chemicals subject to CAA 112(b) or CAA 112(r). California Proposition 65: This product contains no chemicals subject to California Proposition 65. OSHA Hazard Communication Standard (29 CFR 1910.1200): OSHA Status: Hazardous Product (See Section 2 for details). This product has been classified in accordance with the hazard criteria of the USA OSHA Hazard Communication Standard (29CFR 1910.1200) and the Safety Data Sheet contains all the information required by the OSHA Hazard Communication Standard (HazCom 2012). CANADA WHMIS Hazard Symbol and Classification See Section 2 for details. WHMIS Regulatory Status: This product has been classified in accordance with the hazard criteria of the Canadian Hazardous Products Regulations and the Safety Data Sheet contains all the information required by the Hazardous Products Regulations (WHMIS 2015). WHMIS Classification: LVAPCQ LOW VOC SURFACE CLEANER Page 8 of 10 WHMIS 2015 (Canada) Status: Hazardous Product (See Section 2 for details). CEPA - National Pollutant Release Inventory (NPRI): Name CAS No.NPRI Part No. Isopropanol 67-63-0 1A, 5 (VOC) Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components are included or are otherwise exempt from inclusion on this inventory. Comments VOC Content -- See section 9. 16. OTHER INFORMATION Reason for Issue: The Safety Data Sheet was updated. Approved By: Jim Gordon Title: R&D Chemist Prepared By : Regulatory Compliance 'DWHRevised: 08/13/2019 Information Contact: 905-670-5411 Revision Summary: This MSDS replaces the 08/13/2019 MSDS. Revised: Section 1: Reason for Issue. HMIS RATING HEALTH * 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 PERSONAL PROTECTION B NFPA CODES 3 1 0 Manufacturer Supplemental Notes: None Data Sources: Not Available Additional SDS Information: N/AV Not Available N/AP Not Applicable ND Not yet determined ACGIH American Conference of Governmental Industrial Hygienists CAA The Clean Air Act CCCR The Consumer Chemicals and Containers Regulations CEPA The Canadian Environmental Protection Act CERCLA Comprehensive Environmental Response, Compensation, and Liability Act EPCRA The Emergency Planning and Community Right-To-Know Act IARC International Agency for Research on Cancer MSHA Mine Safety and Health Administration NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA The Occupational Safety and Health Administration SARA The Superfund Amendments and Reauthorization Act WHMIS Workplace Hazardous Materials Information System General Statements: None Comments: None Manufacturer Disclaimer: The information contained herein is based on data considered accurate. No warranty LVAPCQ LOW VOC SURFACE CLEANER Page 9 of 10 is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. No responsibility is assumed for personal injury or property damage to vendees or users or third parties, caused by the material. Such vendees or users assume all risks with the use of this material. LVAPCQ LOW VOC SURFACE CLEANER Page 10 of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A5 ! 31- -+-' -- !# < -+0 ' /9 5 , ??A > ? A5 ! -' '..'3!# < -+0 ' /9 5 , ??A > 5;A5 !# < -+ ' /9 5 7@;# < -+ ' /9 * E ' M' &'+3/ : ,M: ' '- ,' - ?7 M? +7-/ E +3/ . 33.' < . 9/'3 M - --31 -33 ' : M -/:B - ;?M - -/;<- 3? 3 <5 CM <-9/ .9 ' C-1- ' ..' 5 M - . -95- .5 ,- / 9136 $%0 3/ .+95- ' . $%* J-1 JM/-1 ! M ??M <-< ?- 1 M 3 " " -./0.'.+ .1 " " -./0.'.+ .1 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product name 2.1 VOC CLEAR COAT Product code 4321-5L Formula date 2015-10-02 Recommended use Coating for professional use Responsible party FinishMaster Inc. 115 W. Washington Street, Suite 700 South Indianapolis, IN 46204 Telephone Product information 317-237-3678 Medical emergency 800-535-5053 Transportation emergency 800-535-5053 2. HAZARDS IDENTIFICATION GHS-Classification Flammable liquids, Category 2 ; Skin corrosion/irritation, Category 2 ; Serious eye damage/eye irritation, Category 2A ; Skin sensitisation, Category 1 ; Toxicity for reproduction, Category 2 ; Target Organ Systemic Toxicant - Single exposure, Category 3 Endpoints which are “not classified”, “cannot classified” and “not applicable” are not shown. GHS-Labelling Hazard symbols: Signal word: Danger Hazard statements:Highly flammable liquid and vapour. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Precautionary statements:Obtain special instructions before use. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ vapours/ spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see supplemental first aid instructions on this label). If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local regulations. Other hazards which do not result in classification Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. The following percentage of the mixture consists of ingredient(s) with unknown acute toxicity: Creation date: 2016-09-14 Page 1 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en 0% 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixture of synthetic resins and solvents Components CAS-No. Chemical name Concentration 108-88-3 Toluene 0.2% 110-43-0 Methyl amyl ketone 4 - 15% 123-86-4 Butyl acetate 1 - 4% 41556-26-7 Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) se- bacate 0.0 - 1.0% 67-64-1 Acetone 15 - 26% 82919-37-7 Decanedioic acid, methyl 1,2,2,6,6- pentamethyl-4-piperidinyl ester 0.0 - 1.0% 97-86-9 Isobutyl methacrylate 0.0 - 1.0% 98-56-6 4-chlorobenzotrifluoride 15 - 26% Any concentration shown as a range is to protect confidentiality or is due to batch variation. Non-regulated ingredients 40 - 50% OSHA Hazardous: Yes 4. FIRST AID MEASURES Eye contact:Remove contact lenses. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart. Seek medical advice. Skin contact:Do NOT use solvents or thinners. Take off all contaminated clothing immediately. Wash skin thoroughly with soap and water or use recognized skin cleanser. If skin irritation persists, call a physician. Inhalation:Avoid inhalation of vapour or mist. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. Ingestion:If swallowed, seek medical advice immediately and show this safety data sheet (SDS) or product label. Do NOT induce vomiting. Keep at rest. Most Important Symptoms/effects, acute and delayed Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. If this product mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, Creation date: 2016-09-14 Page 2 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. If this product is mixed with an isocyanate, skin contact may cause sensitization. Indication of Immediate medical attention and special treatment needed if necessary:No data available on the product. See section 3 and 11 for hazardous ingredients found in the product. 5. FIREFIGHTING MEASURES Suitable extinguishing media:Universal aqueous film-forming foam, Carbon dioxide (CO2), Dry chemical Extinguishing media which shall not be used for safety reasons:High volume water jet Hazardous combustion products:CO, CO2, smoke, and oxides of any heavy metals that are reported in “Composition, Information on Ingredients” section. Fire and Explosion Hazards:Flammable liquid. Vapor/air mixture will burn when an ignition source is present. Special Protective Equipment and Fire Fighting Procedures:Full protective flameproof clothing should be worn as appropriate. Wear self-contained breathing apparatus for firefighting if necessary. In the event of fire, cool tanks with water spray. Do not allow run-off from fire fighting to enter public sewer systems or public waterways. 6. ACCIDENTAL RELEASE MEASURES Procedures for cleaning up spills or leaks:Ventilate area. Remove sources of ignition. Prevent skin and eye contact and breathing of vapor. If the material contains, or is mixed with an isocyanate activator/hardener: Wear a positive-pressure, supplied-air respirator (NIOSH approved TC-19C), eye protection, gloves and protective clothing. Pour liquid decontamination solution over the spill and allow to sit at least 10 minutes. Typical decontamination solutions for isocyanate containing materials are: 20% Surfactant (Tergitol TMN 10) and 80% Water OR 0 -10% Ammonia, 2-5% Detergent and Water (balance) Pressure can be generated. Do not seal waste containers for 48 hours to allow C02 to vent. After 48 hours, material may be sealed and disposed of properly. If material does not contain or is not mixed with an isocyanate activator/hardener: Wear a properly fitted air-purifying respirator with organic vapor cartridges (NIOSH approved TC-23C), eye protection, gloves and protective clothing. Confine, remove with inert absorbent, and dispose of properly. Environmental precautions:Do not let product enter drains. Notify the respective authorities in accordance with local law in the case of contamination of rivers, lakes or waste water systems. 7. HANDLING AND STORAGE Precautions for safe handling:Observe label precautions. Keep away from heat, sparks, flame, static discharge and other sources of ignition. VAPORS MAY IGNITE EXPLOSIVELY. Vapors may spread long distances. Prevent buildup of vapors. Extinguish all pilot lights and turn off heaters, non-explosion proof electrical equipment and other sources of ignition during and after use and until all vapors are gone. Close container after each use. Ground containers when pouring. Wash thoroughly after handling and before eating or smoking. Do not store above 49 C (120 F). If material is a coating: do not sand, flame cut, braze or weld dry coating without a NIOSH approved air purifying respirator with particulate filters or appropriate ventilation, and gloves. Combustible dust clouds may be created where operations Creation date: 2016-09-14 Page 3 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en produce fine material (dust). Avoid formation of significant deposits of material as they may become airborne and form combustible dust clouds. Build up of fine material should be cleaned using gentle sweeping or vacuuming in accordance with best practices. Cleaning methods (e.g. compressed air) which can generate potentially combustible dust clouds should not be used. During baking at temperatures above 400 C, small amounts of hydrogen fluoride can be evolved; these amounts increase as temperatures increase. Hydrogen fluoride vapours are very toxic and cause skin and eye irritation. Above 430 C an explosive reaction may occur if finely divided fluorocarbon comes into contact with metal powder (aluminium or magnesium). Operations such as grinding, buffing or grit blasting may generate such mixtures. Avoid any dust buildup with fluorocarbons and metal mixtures. Advice on protection against fire and explosion:Solvent vapours are heavier than air and may spread along floors. Vapors may form explosive mixtures with air and will burn when an ignition source is present. Always keep in containers of same material as the original one. Never use pressure to empty container: container is not a pressure vessel. The accumulation of contaminated rags may result in spontaneous combustion. Good housekeeping standards and regular safe removal of waste materials will minimize the risks of spontaneous combustion and other fire hazards. Storage Requirements for storage areas and containers:Observe label precautions. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorized access. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Advice on common storage:Store separately from oxidizing agents and strongly alkaline and strongly acidic materials. OSHA/NFPA Storage Classification: IB 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls and work practices:Provide adequate ventilation.This should be achieved by a good general extraction and -if practically feasible- by the use of a local exhaust ventilation.If these are not sufficient to maintain concentrations of particulates and solvent vapour below the OEL, suitable respiratory protection must be worn. National occupational exposure limits CAS-No. Chemical name Source Time Type Value Note 67-64-1 Acetone ACGIH 15 min STEL 750 ppm ACGIH 8 hr TWA 500 ppm OSHA 8 hr TWA 1,000 ppm 110-43-0 Methyl amyl ketone ACGIH 8 hr TWA 50 ppm OSHA 8 hr TWA 100 ppm 123-86-4 Butyl acetate ACGIH 15 min STEL 200 ppm ACGIH 8 hr TWA 150 ppm OSHA 8 hr TWA 150 ppm 108-88-3 Toluene OSHA CEIL 300 ppm OSHA 10 min TWA 500 ppm OSHA 8 hr TWA 200 ppm -- TWA Time-weighted average. STEL Short term exposure limit. CEIL Ceiling. Protective equipment:Personal protective equipment should be worn to prevent contact with eyes, skin or clothing. Respiratory protection: Eye protection:Desirable in all industrial situations. Goggles are preferred to prevent eye irritation. If safety glasses are substituted, include splash guard or side shields. Skin and body protection:Neoprene gloves and coveralls are recommended. Hygiene measures:Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Creation date: 2016-09-14 Page 4 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en Environmental exposure controls:Do not let product enter drains. For ecological information, refer to Ecological Information Section 12. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form:liquid Colour:clear Flash point 14 F Lower Explosive Limit 0.9 % Upper Explosive Limit 12.8 % Evaporation rate Slower than Ether Vapor pressure of principal solvent 59.0 hPa Water solubility appreciable Vapor density of principal solvent (Air = 1)2 Approx. Boiling Range 139 C Approx. Freezing Range Not applicable. Gallon Weight (lbs/gal)8.4 Specific Gravity 1.01 Percent Volatile By Volume 61.86% Percent Volatile By Weight 57.33% Percent Solids By Volume 38.14% Percent Solids By Weight 42.67% pH (waterborne systems only)No data available. Partition coefficient: n-octanol/water No data available Ignition temperature 393 C DIN 51794 Decomposition temperature Not applicable. Viscosity (23 C)Not applicable. ISO 2431-1993 VOC* less exempt (lbs/gal)2.2 VOC* as packaged (lbs/gal)1.2 * VOC less exempt (theoretical) and VOC as packaged (theoretical) are based upon the VOC of the packaged material at the point of manufacture. 10. STABILITY AND REACTIVITY Stability:Stable Conditions to avoid:Stable under recommended storage and handling conditions (see section 7). Materials to avoid:None reasonably foreseeable. Hazardous decomposition products:In the event of fire Carbon monoxide, fluorinated hydrocarbons, hydrogen fluoride, nitrogen oxides may be formed. Hazardous Polymerization:Will not occur. Sensitivity to Static Discharge:Solvent vapors in air may explode if static grounding and bonding is not used during transfer of this product. Sensitivity to Mechanical Impact:None known. Creation date: 2016-09-14 Page 5 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation:May cause nose and throat irritation. May cause nervous system depression characterized by the following progressive steps: headache, dizziness, nausea, staggering gait, confusion, unconsciousness. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. The thermal decomposition vapours of fluorinated polymers may cause polymer fume fever with flu-like symptoms in humans, especially when smoking contaminated tobacco. If this product mixed with an isocyanate activator/hardener (see SDS for the activator), the following health effects may apply: Exposure to isocyanates may cause respiratory sensitization. This effect may be permanent. Symptoms include an asthma-like reaction with shortness of breath, wheezing, cough or permanent lung sensitization. This effect may be delayed for several hours after exposure. Repeated overexposure to isocyanates may cause a decrease in lung function, which may be permanent. Individuals with lung or breathing problems or prior reactions to isocyanates must not be exposed to vapors or spray mist of this product. Ingestion:May result in gastrointestinal distress. Skin or eye contact:May cause irritation or burning of the eyes. Repeated or prolonged liquid contact may cause skin irritation with discomfort and dermatitis. Delayed and immediate effects and also chronic effects from short and long term exposure: Acute oral toxicity not hazardous Acute dermal toxicity not hazardous Acute inhalation toxicity not hazardous % of unknown composition: 0 % Skin corrosion/irritation 4-chlorobenzotrifluoride Category 2 Acetone Category 3 Butyl acetate Category 3 Toluene Category 2 Isobutyl methacrylate Category 2 Serious eye damage/eye irritation 4-chlorobenzotrifluoride Category 2A Acetone Category 2A Isobutyl methacrylate Category 2A Respiratory sensitisation Not classified according to GHS criteria Skin sensitisation Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Category 1 Creation date: 2016-09-14 Page 6 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en Decanedioic acid, methyl 1,2,2,6,6-pentamethyl-4-piperidinyl ester Category 1 Isobutyl methacrylate Category 1 Germ cell mutagenicity Not classified according to GHS criteria Carcinogenicity Not classified according to GHS criteria Toxicity for reproduction Toluene Category 2 Target Organ Systemic Toxicant - Single exposure •Skin Absorption Narcotic effects Toluene •Inhalation airway sensitivity Methyl amyl ketone Narcotic effects Methyl amyl ketone •Ingestion Respiratory tract irritation Methyl amyl ketone Narcotic effects Methyl amyl ketone Target Organ Systemic Toxicant - Repeated exposure Not classified according to GHS criteria Aspiration toxicity Not classified according to GHS criteria Numerical measures of toxicity (acute toxicity estimation (ATE),etc. ):No information available. Symptoms related to the physical, chemical and toxicological characteristics: Exposure to component solvents vapours concentration in excess of the stated occupational exposure limit may result in adverse health effect such as mucous membrane and respiratory system irritation and adverse effect on kidney, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Through skin resorbtion, solvents can cause some of the effects described here. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin. The liquid splashed in the eyes may cause irritation and reversible damage. Whether the hazardous chemical is listed by NTP, IARC or OSHA: 12. ECOLOGICAL INFORMATION There are no data available on the product itself. The product should not be allowed to enter drains or watercourses. Creation date: 2016-09-14 Page 7 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en 13. DISPOSAL CONSIDERATIONS Waste Disposal Method:Do not allow material to contaminate ground water systems. Incinerate or otherwise dispose of waste material in accordance with Federal, State, Provincial, and local requirements. Do not incinerate in closed containers. 14. TRANSPORT INFORMATION International transport regulations IMDG (Sea transport) UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: yes [4-chloro-a,a,a-trifluorotoluene] EmS: F-E,S-E ICAO/IATA (Air transport) UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II DOT UN number: 1263 Proper shipping name: PAINT Hazard Class: 3 Subsidiary Hazard Class: Not applicable. Packing group: II Marine Pollutant: yes [4-chloro-a,a,a-trifluorotoluene] The transport information is for bulk shipments. Exceptions may apply for smaller containers. Matters needing attention for transportation:Confirm that there is no breakage, corrosion, or leakage from the container before shipping. Be sure to prevent damage to cargo by loading so as to avoid falling, dropping, or collapse. Ship in appropriate containers with denotation of the content in accordance with the relevant statutes and rules. 15. REGULATORY INFORMATION Creation date: 2016-09-14 Page 8 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en TSCA Status:In compliance with TSCA Inventory requirements for commercial purposes. DSL Status:All components of the mixture are listed on the DSL. Photochemical Reactivity:Non-photochemically reactive US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65):WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Regulatory information: —————— EPCRA —————– CERCLA CAA CAS # Ingredient 302 TPQ RQ 311/312 313 RQ(lbs) HAP 98-56-6 4-chlorobenzotrifluoride N NR NR C,F,P N NR N 67-64-1 Acetone N NR NR A,C,F N 5,000 N 110-43-0 Methyl amyl ketone N NR NR A,C,F N NR N 123-86-4 Butyl acetate N NR NR A,C,F N NR N 108-88-3 Toluene N NR NR A,C,F,N,P,R Y 1,000 Y 41556-26-7 Bis(1,2,2,6,6- pentamethyl-4- piperidinyl) sebacate N NR NR A,C,F,N,P,R N NR N 82919-37-7 Decanedioic acid, methyl 1,2,2,6,6- pentamethyl-4- piperidinyl ester N NR NR A,C,F,N,P,R N NR N 97-86-9 Isobutyl methacrylate N NR NR A,C,F,N,P,R N NR N 16. OTHER INFORMATION HMIS rating:H: 2 ; F: 3 ; R: 1 Glossary of Terms ACGIH American Conference of Governmental Industrial Hygienists. IARC International Agency for Research on Cancer. NTP National Toxicology Program. OEL Occupational Exposure Limit OSHA Occupational Safety and Health Administration. STEL Short term exposure limit. TWA Time-weighted average. PNOR Particles not otherwise regulated. PNOC Particles not otherwise classified. EPCRA Emergency Planning and Community Right-to-know Act (aka Title III, SARA) 302 Extremely hazardous substances 311/312 Categories F = Fire Hazard A = Acute Hazard R = Reactivity Hazard C = Chronic Hazard P = Pressure Related Hazard 313 Information Section 313 Supplier Notification - The chemicals listed above with a ’Y’ in the 313 column are subject to reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know act of 1986 and of 40 CFR 372. Creation date: 2016-09-14 Page 9 of 10 SAFETY DATA SHEET 4321-5L Version: 1.1 US - en CERCLA Comprehensive Emergency Response, Compensation and Liability Act of 1980. HAP Listed as a Clean Air Act Hazardous Air Pollutant. TPQ Threshold Planning Quantity. RQ Reportable Quantity NA not available NR not regulated NOTE: The list (above) of glossary terms may be modified. Information is accurate and subject to change as new information is received. The information on this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. SDS Prepared by Regulatory Affairs Report version Version:1.1 Changes: Revision Date:2016-07-29 Creation date: 2016-09-14 Page 10 of 10 SAFETY DATA SHEET Prepared according to USA OSHA Hazcom 2012 / Canada WHMIS 2015 Date Issued : 11/16/2017 SDS No : SAPB 3 IN 1 Black Primer 454g_EN Date Revised : 05/13/2021 Revision No : 1 SAPB 3 IN 1 Black Primer, aerosol 1. IDENTIFICATION Product Name: SAPB 3 IN 1 Black Primer, aerosol Product Description: Black Primer, Vehicle Refinishing Product , Aerosol coating 454 g (1 lb) 16 oz General Use: Aerosol Coating, Automotive Use Only Product Stock/Code: SAPB / 24025 Chemical Family: Organic Coating Molecular Formula: Mixture Manufacturer / Supplier Emergency Telephone Numbers (24 hour) Dominion Sure Seal Ltd. 6175 Danville Road, Mississauga Ontario, Canada L5T 2H7 Fax: 905-670-5174 www.dominionsureseal.com Customer Service: 905-670-5411 CANUTEC : (613) 996-6666 CHEMTREC : (800) 424-9300 2. HAZARDS IDENTIFICATION Classification of the substance or mixture The classification and label elements stated below were prepared in accordance with the USA OSHA Hazard Communication Standard (29 CFR 1910.1200; Hazcom 2012) and the Canadian WHMIS regulations (Hazardous Products Regulations; WHMIS 2015). This information may be different from the actual product label information for labels that are regulated by other agencies. Health hazards: Eye Irritation, Category 2 Specific Target Organ Toxicity (Single exposure), Category 3 (Narcotic Effects) Specific Target Organ Toxicity (Repeated exposure), Category 2 Reproductive Toxicity, Category 2 Carcinogenicity, Category 2 Physical hazards: Flammable Aerosols, Category 1 Gases Under Pressure Simple Asphyxiants, Category 1 Label elements Hazardous components for labelling: acetone, isobutyl acetate, toluene, n-butyl acetate, 2-methoxy-1-methylethyl acetate, isopropyl alcohol, carbon black, xylene, mixed isomers and ethylbenzene Page 1 of 14 Flame Gas cylinder Exclamation mark Health hazard Signal Word: DANGER Hazard statement(s) H222: Extremely flammable aerosol. H280: Contains gas under pressure; may explode if heated. H319: Causes serious eye irritation. H336: May cause drowsiness or dizziness. H373: May cause damage to hearing organs and central nervous system through prolonged or repeated exposure. H361: Suspected of damaging the unborn child. H351: Suspected of causing cancer. H600: May displace oxygen and cause rapid suffocation. Precautionary statement(s) Prevention: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P211: Do not spray on an open flame or other ignition source. P251: Pressurized container: Do not pierce or burn, even after use. P264: Wash hands thoroughly after handling. P260: Do not breathe mist, vapours or spray. P271: Use only outdoors or in a well-ventilated area. P280: Wear protective gloves and eye protection. Response: P308+P313: IF exposed or concerned: Get medical advice/attention. P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P362+P364: Take off contaminated clothing and wash it before reuse. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. Storage: P410+P412: Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. Disposal: P501: Dispose of contents/container in accordance with applicable local, regional and/or national regu lations. Hazards Not Otherwise Classified: No data available. Emergency Overview Immediate concerns: Extremely flammable aerosol. Causes serious eye ir ritation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Vapours may cause drowsiness and dizziness. Causes damage to central nervous system and hearing organs through prolonged and repeated exposure. Possible risk of harm to the unborn child. Suspected of causing cancer. Vapor reduces oxygen availability for breathing. SAPB 3 IN 1 Black Primer, aerosol Page 2 of 14 Comments: See sections 9 and 10 for more detailed informatio n on physicochemical effects. See section 11 for more detailed information on health effects. See sections 12 for more detailed information on en vironmental effects. The actual container label may not include the above label elements. The labeling shown above applies to products used solely for industrial / professional use. Consumer products should be labeled in accordance with the Canadian Consumer Chemicals and Containers Regulations and US Consumer Product Safety Commission regulations. Consumer product labeling takes precedence over Canadian WHMIS 2015 and OSHA Hazcom 2012 Hazard Communication labeling. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name Wt.%CAS number acetone 34 - 37 67-64-1 propane 14.5 - 16.5 74-98-6 talc 12 - 13 14807-96-6 isobutyl acetate 11.5 - 12.5 110-19-0 isobutane 6.5 - 7.5 75-28-5 toluene 3.5 - 4.5 108-88-3 n-butyl acetate 2 - 3 123-86-4 2-methoxy-1-methylethyl acetate 1.5 - 2 108-65-6 isopropyl alcohol 1 - 1.5 67-63-0 carbon black 1 - 1.5 1333-86-4 xylene, mixed isomers 0.7 - 0.9 1330-20-7 phosphoric acid 0.4 - 0.6 7664-38-2 ethylbenzene 0.15 - 0.25 100-41-4 Comments: There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the product and hence require reporting in this section. xylene, mixed isomers is a complex substance i.e. complex mixture of known or unknown composition. ethylbenzene is a hazardous constituent that may be contained in the complex substance at 18 to 20% w/w. 4. FIRST AID MEASURES Eye Contact: In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at least 15 minutes. Get medical attention, if irritation persists. Skin Contact: Wash with soap and water. Get medical attention if irritation develops or persists. Remove contaminated clothing and wash before reuse. Ingestion: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Signs and Symptoms of Overexposure Eye Contact: Contact causes serious eye irritation. Symptoms ma y include pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Skin Contact: Prolonged or repeated contact may cause skin irrit ation. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Ingestion: Substance may be harmful if swallowed. May cause irritation. Symptoms of ingestion may include abdominal pain, nausea, vomiting and diarrhea. SAPB 3 IN 1 Black Primer, aerosol Page 3 of 14 Inhalation: High vapor or spray mist concentrations may be harmful if inhaled. May cause headaches and dizziness. High vapor concentrations may cause drowsiness. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and loss of consciousness). Repeated or prolonged inhalation may cause toxic effects. High vapor concentrations can displace oxygen in enclosed spaces and cause asphyxiation. Notes to Physician: Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. Additional Information: No data available. 5. FIRE FIGHTING MEASURES Flammable Properties: Extemely flammable aerosol. Can readily form explosive mixtures at or above the flash point. Product can be ignited by static discharge. Extinguishing Media: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Hazardous Combustion Products: During a fire, irritating and highly toxic gases m ay be generated by thermal decomposition or combustion. Fire Fighting Procedures: Containers can build up pressure if exposed to hea t (fire). Fire Fighting Equipment: As in any fire, wear self-contained breathing appa ratus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. Sensitivity to Static Discharge: Product is sensitive to static discharge. Sensitivity to Mechanical Impact: Product is sensitive to mechanical impact. Do not puncture container. Contents under pressure. Do not expose to heat or store above 120°F (49°C). 6. ACCIDENTAL RELEASE MEASURES Small Spill: Eliminate all ignition sources. Contain spilled li quid with sand or earth. DO NOT use combustible materials such as sawdust. Sweep up material being careful not to raise dust. Place in an appropriate disposal container and seal tightly. Environmental Precautions Water Spill: Do not flush to sewer. Land Spill: Avoid runoff into storm sewers and ditches which lead to waterways. Special Protective Equipment: Clean up spills immediately, observing precautions in Protective Equipment section 8. 7. HANDLING AND STORAGE General Procedures: Comply with all national, state, and local codes p ertaining to the storage, handling, dispensing, and disposal of flammable liquids. Handling: Contents under pressure. Do not expose to heat or store above 120°F (49°C). Use only in a well ventilated area. Do not use in the presence of open flame or spark. Do not puncture container. Do not breath vapors or spray mist. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Wash thoroughly after handling. Storage: Keep away from heat and flame. Store in a cool dry place. Container may explode if heated. Do not incinerate. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines OSHA / WHMIS 2015 HAZARDOUS COMPONENTS Occupational Exposure Limits SAPB 3 IN 1 Black Primer, aerosol Page 4 of 14 Chemical Name Type ppm mg/m3 acetone OSHA PEL TWA 1000 2400 ACGIH TLV TWA 500 1188 STEL 750 1782 NIOSH REL TWA 250 590 propane OSHA PEL TWA 1000 1800 ACGIH TLV TWA 1000 -- NIOSH REL TWA 1000 1800 talc OSHA PEL TWA -- [1]2 [1] ACGIH TLV TWA -- [1]2 [1] NIOSH REL TWA -- [1]2 [1] isobutyl acetate OSHA PEL TWA 150 700 ACGIH TLV TWA 150 713 NIOSH REL TWA 150 700 isobutane ACGIH TLV STEL 1000 -- NIOSH REL TWA 800 1900 toluene OSHA PEL TWA 200 -- STEL 300 -- ACGIH TLV TWA 20 75 NIOSH REL TWA 100 375 STEL 150 560 n-butyl acetate OSHA PEL TWA 150 710 STEL 200 950 NIOSH REL TWA 150 710 STEL 200 950 2-methoxy-1-methylethyl acetate USA OEL --- [2]-- [2] EU OEL TWA 50 275 STEL 100 550 isopropyl alcohol OSHA PEL TWA 400 980 ACGIH TLV TWA 200 491 STEL 400 984 NIOSH REL TWA 400 980 STEL 500 1225 carbon black OSHA PEL TWA --3.5 ACGIH TLV TWA -- [3]3.5 [3] NIOSH REL TWA --3.5 phosphoric acid OSHA PEL TWA --1 SAPB 3 IN 1 Black Primer, aerosol Page 5 of 14 phosphoric acid ACGIH TLV TWA --1 STEL --3 NIOSH REL TWA --1 STEL --3 ethylbenzene OSHA PEL TWA 100 435 ACGIH TLV TWA 20 87 NIOSH REL TWA 100 435 STEL 125 545 Footnotes: 1. Dust - respirable fraction. 2. This material does not have established exposure limits in the USA under OSHA, NIOSH, ACGIH. 3. Inhalable particulate matter. Engineering Controls: Use general or local exhaust ventilation to mainta in air concentrations below recommended exposure limits. Avoid breathing mists; if general ventilation or local exhaust is inadequate, persons exposed to mists should wear approved breathing devices. If user operations generate dust during sanding of this product, use ventilation to keep exposure to airborne dust below the above exposure limits. Personal Protective Equipment Eyes and Face: Wear safety glasses with side shields (or goggles). Skin Contact: Wear chemical resistant gloves. Neoprene is recomm ended. Avoid prolonged or repeated contact with skin. Respiratory: If engineering controls do not maintain airborne c oncentrations below recommended exposure limits, an approved respirator must be worn. Respirator type: Air-purifying respirator with an appropriate, government approved, air-purifying filter, cartridge or canister. Protective Clothing: Not applicable for aerosol containers. Work Hygienic Practices: Use good personal hygiene practices. Wash hands be fore eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing/wash thoroughly before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State : Liquid, without aerosol propellants Odor : Ketone Odor Threshold : No data available. Appearance : Aerosol Color : Black pH : Not Applicable % Volatiles : 80 to 81% w/w Flash Point and Method : -18°C Setaflash Closed Cup, acetone [lowest known value of aerosol concentrate] Flammable Limits : 1.0 to 12.8 Notes: Based on data for acetone Autoignition Temperature : 480°C Notes: Based on data for acetone [lowest known value of a erosol concentrate] Vapor Pressure : 50 - 60 psig at 20°C Vapor Density : > 1 (air = 1) SAPB 3 IN 1 Black Primer, aerosol Page 6 of 14 Boiling Point : 56°C (acetone) [lowest known value of aerosol conc entrate] Freezing Point : No data available. Solubility in Water : Partial Evaporation Rate (n-butyl acetate = 1) : > 1 Density : 1.08 - 1.09 g/ml at 20°C Notes: An estimate for the aerosol concentrate density Viscosity : > 100 cps at 20°C VOC Content : 44.5 - 45.5% w/w (< 370 g/l), less exempts Oxidizing Properties : None Comments: Flammability Statement: The flammability of an aerosol is determined by its flame extension and/or flashback. Flammability:Yes Aerosol Flame Projection:> 15 cm but < 100 cm Flashback:Yes Calculated Aerosol Chemical Heat of Combustion, kJ/g 25 to 27 VOC Compliance Statement Total Volatiles:< 660 g/l 80 - 81% w/w VOC Content:Product-Weighted Reactivity (PWR): 0.70 g O3/g product Product-Weighted MIR (PWMIR): 0.64 g O3/g product (CA) [44.5 – 45.5% w/w (< 370 g/l), less exempts] VOC Regulation:USA National VOC Emission Standards for Aerosol Coatings – 40CFR PART 59 SUBPART E Coating Category:Auto Body Primer The VOC content meets the 1.55 PWR category limit for Auto Body Primer. USA compliant. VOC Regulation:California – Regulation for Reducing the Ozone from Aerosol Coating Product Emissions – Title 17, California Coating Category:Auto Body Primer The VOC content meets the 0.95 PWMIR category limit for Auto Body Primer. California compliant. 10. STABILITY AND REACTIVITY Reactive Hazard : No Hazardous Polymerization: Not expected to occur. Stability: Stable. Conditions to Avoid: Keep away from flames and any object that sparks. Container may expode if heated. Possibility of Hazardous Reactions: No data available. Hazardous Decomposition Products: Carbon Monoxide and other toxic vapors. Incompatible Materials: Oxidizing materials. SAPB 3 IN 1 Black Primer, aerosol Page 7 of 14 11. TOXICOLOGICAL INFORMATION Acute Toxicity Chemical Name Oral LD 50 mg/kg(rat) Dermal LD 50 mg/kg(rabbit) Inhalation LC 50 mg/l acetone 8400 5250(mouse) 5300(rabbit) >15,700 50.1(rat;8h) 44.0(mouse;4h) propane Not Applicable Not Applicable >800,000 ppm (rat,15m) [>1443 mg/L] talc Not classified. Not classified. Not classified. isobutyl acetate > 13,400 > 17,400 > 14.72(rat;6h) > 13.24(rat;6h) isobutane Not Applicable Not Applicable 658(rat;4h) 570,000 ppm (rat;15m) 680(mouse;2h) toluene 7000 6400 5500 12,270 49.0(rat;4h) 30.0(mouse;2h) 19.9(mouse;7h) n-butyl acetate 13,100(rat) 11,000(rat) >14,400 >45.0(rat;4h) 2-methoxy-1-methylethyl acetate >10,000 8532 13,700 >5000(rat) >19,400(rbt) 10.8(rat;3h) 23.5(rat;6h) [no deaths] isopropyl alcohol 4710-5840 4475(mouse) 5030(rabbit) 12,870 51.0(rat;8h) 72.6(rat;4h) carbon black > 15,400 > 3000 Not Applicable xylene, mixed isomers 5400 5251(mouse) 5627(mouse) 12,180 6350 ppm (rat;4h) 6700 ppm (rat;4h) phosphoric acid 1530 2740 1.69(rat;1h - mist) ethylbenzene 5460 3500 5627(mouse) 17,800 15,354 17.2(rat;4h) 13,367 ppm (rat;2h) Acute Toxicity - Dermal LD50 : Based on available ingredient data, the classifica tion criteria for Acute Dermal Toxicity are not met for this mixture. The calculated ATE is >2000 mg/kg. Acute Toxicity - Oral LD50 : Based on available ingredient data, the classifica tion criteria for Acute Oral Toxicity are not met for this mixture. The calculated ATE is >2000 mg/kg. Acute Toxicity - Inhalation LC50 : Based on available ingredient data, the classifica tion criteria for Acute Toxicity - inhalation are not met for this mixture. The calculated ATE is >20 mg/l/4h (vapours) and >5 mg/l/4h (mists). High vapor concentrations may be harmful if inhaled. Excessive vapor concentrations are attainable. Saturated vapors can be encountered in confined spaces and/or under conditions of poor ventilation. Notes: <5 % of the mixture consists of an ingredient or ingredients of unknown acute toxicity. No additional toxicology information is available for this product itself. (See Component Toxicity Information). Primary Routes of Entry: SAPB 3 IN 1 Black Primer, aerosol Page 8 of 14 Eye contact. Skin contact. Inhalation. Skin Irritation / Corrosion: Based on available data, the classification criter ia for skin irritation are not met for this mixture. Substance does not generally irritate and is only mildly irritating to the skin. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Eye Irritation / Serious Eye Damage: Contains: acetone and isopropyl alcohol. Contact causes serious eye irritation. The mixture is classified as: Eye Irritant, category 2, based on summation of ingredient data (>10% ingredients classified as eye irritant, category 2). Liquid, aerosols and vapors of this product are irritating and can cause pain, tearing, reddening and swelling accompanied by a stinging sensation and/or a feeling like that of fine dust in the eyes. Respiratory / Skin Sensitizer: Based on available data, the classification criter ia for respiratory sensitization are not met for this mixture (< 0.1% ingredients classified as a respiratory sensitizer, category 1 or sub -category 1A and < 1.0% ingredients classified as a respiratory sensitizer, sub-category 1B). Based on available data, the classification criteria for skin sensitization are not met for this mixture (< 0.1% ingredients classified as a skin sensitizer, category 1 or sub-category 1A and < 1.0% ingredients classified as a skin sensitizer, sub-category 1B). Germ Cell Mutagenicity: Based on available data, the classification criter ia for Germ Cell Mutagenicity are not met for this mixture (< 0.1% ingredients classified as Germ Cell Mutagen, category 1A or 1B and < 1.0% ingredients classified as Germ Cell Mutagen, category 2). Carcinogenicity Chemical Name NTP status IARC status OSHA status Other acetone ------A4 (ACGIH) propane -------- talc --3 --A4 (ACGIH) isobutyl acetate -------- isobutane -------- toluene --3 --A4 (ACGIH) n-butyl acetate -------- 2-methoxy-1-methylethyl acetate -------- isopropyl alcohol --3 ---- carbon black --2B --A3 (ACGIH) xylene, mixed isomers --3 ---- phosphoric acid -------- ethylbenzene --2B --A3 (ACGIH) Notes: The mixture is classified as: Carcinogenicity, cat egory 2 based on ingredient data using the applicable cut- off/concentration limits (≥ 0.1% ingredients classified as a Carcinogen, category 2). carbon black and ethylbenzene are listed as Group 2B (possibly carcinogenic to humans) by IARC. Reproductive Toxicity: Contains: toluene. The mixture is classified as: R eproductive Toxicity, category 2 based on ingredient data using the applicable cut-off/concentration limits (≥ 0.1% ingredients classified as Reproductive Toxicity, category 2). May cause adverse reproductive effects. Suspected of damaging the unborn child. Specific Target Organ Toxicity - Single Exposure: Contains: acetone, isobutyl acetate, toluene, n-b utyl acetate and isopropyl alcohol. The mixture is classified as: Specific Target Organ Toxicity - Single E xposure, category 3, based on summation of ingredient data using the applicable cut-off/concentration limits (≥ 20% SAPB 3 IN 1 Black Primer, aerosol Page 9 of 14 summation of all ingredients classified as Specific Target Organ Toxicity - Single Exposure, category 3 [Narcotic Effects]). Can cause central nervous system depression (including unconsciousness). High vapor concentrations may cause drowsiness. May cause headaches and dizziness. Specific Target Organ Toxicity - Repeated Exposure: Contains: toluene, xylene, mixed isomers and ethylbenzene. The mixture is classified as: Specific Target Organ Toxicity - Repeated Exposure, category 2, based on ingredient data using the applicable cut-off/concentration limits (≥ 1.0% ingredients classified as Specific Target Organ Toxicity - Repeated Exposure, category 2). Pr olonged inhalation may be harmful. Chronic exposure to organic solvents such as Toluene, Xylene and Ethylbenzene have been associated with various neurotoxic effects including permanent brain and nervous system damage. Symptoms include: loss of memory, loss of intellectual ability, and loss of coordination. Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Aspiration Hazard: Based on available data, the classification criter ia for Aspiration Hazard are not met for this mixture (< 10% ingredients classified as an Aspiration Hazard, category 1 and/or mixture viscosity > 20.5 mm 2/s at 40 °C). 12. ECOLOGICAL INFORMATION Environmental Data: No data available. Ecotoxicological Information: No data available. Bioaccumulation/Accumulation: No data available. Distribution: No data available. Aquatic Toxicity (Acute): No data available. Chemical Fate Information: No data available. 13. DISPOSAL CONSIDERATIONS Disposal Method: Comply with applicable local, state or internation al regulations concerning solid or hazardous waste disposal and/or container disposal. Do not discharge substance/product into sewer system. Product Disposal: When container is empty, press button to release a ll pressure, then dispose of container and unused contents in accordance with Local, Provincial/State and Federal regulations. 14. TRANSPORT INFORMATION DOT (Department of Transportation) Proper Shipping Name : AEROSOLS Primary Hazard Class/Division: 2.1 UN/NA Number : 1950 Packing Group : N/AP Other Shipping Information: With an inner packaging < 1.0 L, this product may be shipped as a Limited Quantity as per DOT 173.306. Vessel (IMO/IMDG) Shipping Name : AEROSOLS UN/NA Number : 1950 Primary Hazard Class/Division: 2.1 Packing Group : N/AP Marine Pollutant : None Label : None Note: With an inner packaging < 1.0 L, this product may be shipped as a Limited Quantity. SAPB 3 IN 1 Black Primer, aerosol Page 10 of 14 Canadian Transportation of Dangerous Goods Regulations Shipping Name : AEROSOLS UN/NA Number : 1950 Primary Hazard Class/Division: 2.1 Packing Group : N/AP TDG Note: With an inner packaging < 1.0 L, this component may be shipped as a Limited Quantity as per TDG Section 1.17. 15. REGULATORY INFORMATION UNITED STATES SARA Section 311/312 Hazard Categories 311/312 HEALTH HAZARDS: Carcinogenicity, Eye Irritation, Narcotic Effects, Reproductive Toxicity, Simple Asphyxiants, Target Organ Toxicity (Repeated exposure) 311/312 Physical Hazards: Flammable Aerosols, Gases Under Pressure EPCRA Section 313 Toxic Chemicals Chemical Name Wt.%CAS nu mber toluene 3.5 - 4.5 108-88-3 isopropyl alcohol 1 - 1.5 67-63-0 EPCRA Section 302 Extremely Hazardous Substances EPCRA Status: This product contains no listed extremely hazardous substances that are subject to the reporting requirements of SARA Title III, Section 302. CERCLA Hazardous Substances and Reportable Quant ities (RQ) Chemical Name Wt.%RQ acetone 34 - 37 5,000 isobutyl acetate 11.5 - 12.5 5,000 toluene 3.5 - 4.5 1,000 n-butyl acetate 2 - 3 5,000 xylene, mixed isomers 0.7 - 0.9 100 phosphoric acid 0.4 - 0.6 5,000 ethylbenzene 0.15 - 0.25 1,000 TSCA (The Toxic Substances Control Act) TSCA Status: All components are included or are otherwise exempt from inclusion on this inventory. CAA 112(b) - Hazardous Air Pollutants SAPB 3 IN 1 Black Primer, aerosol Page 11 of 14 Chemical Name Wt.%CAS num ber toluene 3.5 - 4.5 108-88-3 xylene, mixed isomers 0.7 - 0.9 1330-20-7 ethylbenzene 0.15 - 0.25 100-41-4 CAA 112(r) - List of Substances for Accidental Rele ase Prevention: Name CAS No.Threshold Qty (TQ) Propane 74-98-6 10,000 Butane 75-28-5 10,000 California Proposition 65: WARNING: This product can expose you to chemicals including the chemical(s) listed below, which is [are] known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. Chemical Name Wt.%Listed toluene 3.5 - 4.5 Developmental Toxicity Female Reproductive carbon black 1 - 1.5 Cancer ethylbenzene 0.15 - 0.25 Cancer OSHA Hazard Communication Standard (29 CFR 1910.1200): OSHA Status: Hazardous Product (See Section 2 for details). This product has been classified in accordance with the hazard criteria of the USA OSHA Hazard Communication Standard (29CFR 1910.1200) and the Safety Data Sheet contains all the information required by the OSHA Hazard Communication Standard (HazCom 2012). CANADA WHMIS Hazard Symbol and Classification See Section 2 for details. WHMIS Regulatory Status: This product has been classified in accordance with the hazard criteria of the Canadian Hazardous Products Regulations and the Safety Data Sheet contains all the information required by the Hazardous Products Regulations (WHMIS 2015). WHMIS Classification: WHMIS 2015 (Canada) Status: Hazardous Product (See Section 2 for details). CEPA - National Pollutant Release Inventory (NPRI): SAPB 3 IN 1 Black Primer, aerosol Page 12 of 14 Name CAS No.NPRI Part No. isobutyl acetate 110-19-0 5 (VOC) toluene 108-88-3 1A, 5 (VOC) n-butyl acetate 123-86-4 5 (VOC) 2-methoxy-1-methylethyl acetate 108-65-6 5 (VOC) isopropyl alcohol 67-63-0 1A, 5 (VOC) propane 74-98-6 5 (VOC) isobutane 75-28-5 5 (VOC) Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components are included or are otherwise exempt from inclusion on this inventory. Comments VOC Content -- See section 9. 16. OTHER INFORMATION Reason for Issue: The Safety Data Sheet was updated. Approved By: Jim Gordon Title: R&D Chemist / Chemiste de R&D / Químico de Investigación y Desarrollo Prepared By : Regulatory Compliance Date5HYLVHG Information Contact: 905-670-5411 Revision Summary: This MSDS replaces the 05/13/2021 MSDS. HMIS RATING HEALTH * 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 PERSONAL PROTECTION B NFPA CODES 3 2 0 NFPA 30 / 30B Storage Classification: Level 2 Aerosol Manufacturer Supplemental Notes: None Data Sources: Not Available Additional SDS Information: N/AV Not Available N/AP Not Applicable ND Not yet determined ACGIH American Conference of Governmental Industrial Hygienists CAA The Clean Air Act CCCR The Consumer Chemicals and Containers Regulations CEPA The Canadian Environmental Protection Act CERCLA Comprehensive Environmental Response, Compensation, and Liability Act EPCRA The Emergency Planning and Community Right-To-Know Act IARC International Agency for Research on Cancer MSHA Mine Safety and Health Administration SAPB 3 IN 1 Black Primer, aerosol Page 13 of 14 NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA The Occupational Safety and Health Administration SARA The Superfund Amendments and Reauthorization Act WHMIS Workplace Hazardous Materials Information System General Statements: None Comments: None Manufacturer Disclaimer: The information contained herein is based on data considered accurate. 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